Indium substitution effect on the topological crystalline insulator family (Pb1−x_{1-x}Snx_{x})1−y_{1-y}Iny_{y}Te: Topological and superconducting properties

Topological crystalline insulators (TCIs) have been of great interest in the area of condensed matter physics. We investigated the effect of indium substitution on the crystal structure and transport properties in the TCI system (Pb$_{1-x}$Sn$_{x}$)$_{1-y}$In$_{y}$Te. For samples with a tin concentration $x\le50\%$, the low-temperature resisitivities show a dramatic variation as a function of indium concentration: with up to ~2% indium doping the samples show weak-metallic behavior, similar to their parent compounds; with ~6% indium doping, samples have true bulk-insulating resistivity and present evidence for nontrivial topological surface states; with higher indium doping levels, superconductivity was observed, with a transition temperature, Tc, positively correlated to the indium concentration and reaching as high as 4.7 K. We address this issue from the view of bulk electronic structure modified by the indium-induced impurity level that pins the Fermi level. The current work summarizes the indium substitution effect on (Pb,Sn)Te, and discusses the topological and superconducting aspects, which can be provide guidance for future studies on this and related systems.Comment: 16 pages, 8 figure

Nanocalorimetric Evidence for Nematic Superconductivity in the Doped Topological Insulator Sr0.1_{0.1}Bi2_{2}Se3_{3}

Spontaneous rotational-symmetry breaking in the superconducting state of doped $\mathrm{Bi}_2\mathrm{Se}_3$ has attracted significant attention as an indicator for topological superconductivity. In this paper, high-resolution calorimetry of the single-crystal $\mathrm{Sr}_{0.1}\mathrm{Bi}_2\mathrm{Se}_3$ provides unequivocal evidence of a two-fold rotational symmetry in the superconducting gap by a \emph{bulk thermodynamic} probe, a fingerprint of nematic superconductivity. The extremely small specific heat anomaly resolved with our high-sensitivity technique is consistent with the material's low carrier concentration proving bulk superconductivity. The large basal-plane anisotropy of $H_{c2}$ is attributed to a nematic phase of a two-component topological gap structure $\vec{\eta} = (\eta_{1}, \eta_{2})$ and caused by a symmetry-breaking energy term $\delta (|\eta_{1}|^{2} - |\eta_{2}|^{2}) T_{c}$. A quantitative analysis of our data excludes more conventional sources of this two-fold anisotropy and provides the first estimate for the symmetry-breaking strength $\delta \approx 0.1$, a value that points to an onset transition of the second order parameter component below 2K